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The earliest detections of interstellar and cometary species were made via electronic
spectroscopy in the
UV-visible
region rather than rotational spectroscopy in the microwave and sub-mm regions. The
brief report in 1941 of the
identification of CH+ by Alex Douglas and
Gerhard Herzberg alludes to
an informal gathering at Yerkes Observatory
at which Pol Swings reported that several lines
near 4000 Å could not be matched with known spectra. Herzberg and
Edward Teller noted the similarity to the
isoelectronic species
BH and suggested that
CH+ could be the source of the lines. New spectra taken by Douglas & Herzberg at the
University of Saskatchewan confirmed the identification.
Swings used the same spectra to
determine that CH+ was also present in comets. In 1987,
Magain & Gillet reported the
detection of CH+ in the
Large Magellanic Cloud. It has also been
detected with rotational spectroscopy by
Cernicharo et al.
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