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Labeling HCCS as the "thioketenyl radial" is perhaps a bit limiting, since HCCS is the
radical precursor to both thioketene, a known astromolecule, and
ethynethiol, which
has not been detected to date. The linear alignment of the four atoms in HCCS is more suggestive of
ethynethiol. As evident in the image shown here of the singly occupied &pi orbital of HCCS, radical
character is present on both the sulfur atom and the carbon atom bonded to hydrogen.
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